| THE FRANK LLOYD WRIGHT FOUNDATION | Scottsdale | B43 Education | $9.6M | 7 |
| GOMPERS | Phoenix | B28Z Education | $9.6M | 1 |
| VERANO LEARNING PARTNERS | Chandler | B29 Education | $9.5M | 1 |
| VILLA MONTESSORI INC | Phoenix | B21Z Education | $9.5M | 1 |
| THE GREATHEARTS FOUNDATION INC | Phoenix | B11 Education | $9.5M | 2 |
| DESERT CABALLEROS WESTERN MUSEUM | Wickenburg | — | $9.4M | 1 |
| GLOBAL TRAINING NETWORK INC | Peoria | X20 Religion-Related | $9.4M | 2 |
| IMAGINE CHARTER ELEMENTARY AT DESERT WEST INC | Phoenix | B29 Education | $9.4M | 1 |
| SERVTECH | Gilbert | P20 Human Services | $9.4M | 0 |
| CALIFORNIA SMALL MANUFACTURING HEALTH AND WELFARE TRUST FUND | Phoenix | Y43 Mutual & Membership Benefit | $9.3M | 0 |
| LEGACY TRADITIONAL SCHOOL - SAN TAN | Chandler | B20 Education | $9.3M | 0 |
| BROPHY COMMUNITY FOUNDATION | Phoenix | B82 Education | $9.3M | 1 |
| SUN CITY AREA INTERFAITH SERVICES INC DBA BENEVILLA | Surprise | P750 Human Services | $9.3M | 4 |
| Southeastern Arizona Behavioral Health Services Inc | Benson | F99Z Mental Health & Crisis Intervention | $9.2M | 6 |
| AHEARN FAMILY FOUNDATION | Phoenix | T20 Philanthropy, Voluntarism & Grantmaking Foundations | $9.2M | 0 |
| BHHS Legacy Foundation | Phoenix | — | $9.2M | 3 |
| SUPIMA | Tempe | — | $9.2M | 2 |
| INSTITUTE FOR DIGITAL INCLUSION ACCELERATION | Tempe | W20 Public & Societal Benefit | $9.2M | 0 |
| JEWISH COMMUNITY ASSOCIATION OF GREATER PHOENIX | Scottsdale | T50 Philanthropy, Voluntarism & Grantmaking Foundations | $9.1M | 5 |
| City Help Inc of Phoenix | Phoenix | P20 Human Services | $9M | 3 |
| ARIZONA MAJOR EVENTS HOST COMMITTEE | Phoenix | S99 Community Improvement & Capacity Building | $9M | 0 |
| LIVING UNITED FOR CHANGE IN ARIZONA | Phoenix | P99 Human Services | $9M | 4 |
| GAP COMMUNITY SERVICES | Tucson | P40 Human Services | $9M | 6 |
| CHRISTIAN CARE RETIREMENT APARTMENTS INC | Phoenix | — | $8.9M | 7 |
| Catholic Community Foundation for the Diocese of Phoenix | Tempe | X122 Religion-Related | $8.9M | 2 |
| THE GRANDE INNOVATION ACADEMY | Casa Grande | B28 Education | $8.9M | 2 |
| RIALTO THEATRE FOUNDATION | Tucson | A65 Arts, Culture & Humanities | $8.8M | 0 |
| EDUCATIONAL OPTIONS FOUNDATION | Tempe | B25 Education | $8.8M | 3 |
| PINAL HISPANIC COUNCIL | Tucson | F210 Mental Health & Crisis Intervention | $8.8M | 5 |
| North Valley Christian Academy | Phoenix | B90 Education | $8.8M | 1 |
| LEGACY TRADITIONAL SCHOOL - PEORIA | Chandler | B29 Education | $8.8M | 1 |
| LAPAN MEMORIAL SUNSHINE FOUNDATION INC C/O DAVID LAPAN | Tucson | T20 Philanthropy, Voluntarism & Grantmaking Foundations | $8.7M | 1 |
| THE VILLAGES AT ESTRELLA MOUNTAIN RANCH COMMUNITY ASSOCIATION | Scottsdale | S99 Community Improvement & Capacity Building | $8.7M | 0 |
| MATH AND SCIENCE SUCCESS ACADEMY INC | Tempe | B29 Education | $8.7M | 2 |
| TAKE CHARGE AMERICA INC | Phoenix | P51 Human Services | $8.7M | 5 |
| ABT PERFORMING ARTS ASSOCIATION INC | Peoria | A650 Arts, Culture & Humanities | $8.6M | 3 |
| BOYS & GIRLS CLUB OF GREATER SCOTTSDALE INC | Scottsdale | O210 Youth Development | $8.6M | 9 |
| International Brotherhood of 104 TCWH | Phoenix | — | $8.6M | 13 |
| TLC TRANSITIONAL LIVING COMMUNITIES | Mesa | — | $8.6M | 1 |
| CHANDLER PREPARATORY ACADEMY | Phoenix | B29 Education | $8.6M | 1 |
| Sheet Metal Air Rail and Transportation Works Local Union 359 | Phoenix | J40 Employment | $8.6M | 2 |
| THE ARIZONA ANIMAL WELFARE LEAGUE | Phoenix | D200 Animal-Related | $8.6M | 1 |
| AJO AMBULANCE INC | Ajo | P20 Human Services | $8.5M | 1 |
| ARCHWAY CLASSICAL ACADEMY VERITAS | Phoenix | B29 Education | $8.5M | 2 |
| IMAGINE COOLIDGE ELEMENTARY INC | Coolidge | B29 Education | $8.5M | 2 |
| CPLC NEVADA INC | Phoenix | S30 Community Improvement & Capacity Building | $8.5M | 11 |
| PHOENIX FINAL FOUR LOCAL ORGANIZING COMMITTEE | Phoenix | N70 Recreation & Sports | $8.5M | 0 |
| MOHAVE ACCELERATED LEARNING CENTER | Bullhead City | B29 Education | $8.5M | 2 |
| NOURISHPHX | Phoenix | P600 Human Services | $8.5M | 1 |
| NATIVE AMERICANS FOR COMMUNITY ACTION INC | Flagstaff | — | $8.5M | 7 |
