| TUCSON JEWISH COMMUNITY CENTER INC | Tucson | P280 Human Services | $15.1M | 6 |
| UNITED ARIZONA FIREFIGHTERS HEALTH CARE TRUST | Tempe | Y43 Mutual & Membership Benefit | $15M | 0 |
| The Primavera Foundation Inc | Tucson | L250 Housing & Shelter | $15M | 4 |
| LEGACY TRADITIONAL SCHOOL - GLENDALE | Chandler | B29 Education | $15M | 1 |
| EMPOWER COLLEGE PREP | Phoenix | B29 Education | $15M | 4 |
| CAMPUS RESEARCH CORPORATION | Tucson | B43P Education | $14.9M | 11 |
| LEGACY TRADITIONAL SCHOOL - MARICOPA | Chandler | B90 Education | $14.9M | 0 |
| MARICOPA COUNTY COMMUNITY COLLEGE DISTRICT FOUNDATION | Tempe | T31 Philanthropy, Voluntarism & Grantmaking Foundations | $14.9M | 1 |
| LEGACY TRADITIONAL SCHOOL - NW TUCSON | Chandler | B29 Education | $14.7M | 1 |
| ANTHEM COMMUNITY COUNCIL INC | Anthem | S22 Community Improvement & Capacity Building | $14.7M | 1 |
| HELP-NEW MEXICO INC | Phoenix | — | $14.7M | 10 |
| TROON COUNTRY CLUB INC | Scottsdale | — | $14.7M | 5 |
| MARYVALE PREPARATORY ACADEMY | Phoenix | B29 Education | $14.6M | 2 |
| FOUNDATION FOR BLIND CHILDREN | Phoenix | G41Z Diseases, Disorders & Medical Disciplines | $14.6M | 8 |
| PRISMA COMMUNITY CARE (FKA SOUTHWEST CENTER HIV/AIDS INC) | Phoenix | E99Z Health Care | $14.6M | 7 |
| CAREER SUCCESS SCHOOLS INC | Scottsdale | B29 Education | $14.6M | 3 |
| THE ESTANCIA CLUB INC | Scottsdale | N50 Recreation & Sports | $14.6M | 9 |
| Utah-Idaho Teamsters Retirees' Trust | Phoenix | — | $14.5M | 0 |
| LANDINGS CREDIT UNION | Tempe | — | $14.5M | 16 |
| ARIZONA STATE UNIVERSITY RESEARCH PARK INC | Scottsdale | B43I Education | $14.5M | 4 |
| TUCSON RESIDENCE FOUNDATION INC | Tucson | — | $14.4M | 5 |
| MIKID-Mentally Ill Kids in Distress | Phoenix | — | $14.3M | 4 |
| VALLEY VIEW COMMUNITY FOOD ASSISTANCE | Sun City | — | $14.3M | 0 |
| CHILDREN'S CLINICS FOR REHABILITATIVE SERVICES | Tucson | E320 Health Care | $14.1M | 7 |
| ASU ENTERPRISE PARTNERS | Tempe | B11 Education | $14.1M | 11 |
| UNITED FOOD AND COMMERCIAL WORKERS UNION LOCAL NO 99 | Phoenix | — | $14.1M | 20 |
| APS Foundation Inc | Phoenix | T20 Philanthropy, Voluntarism & Grantmaking Foundations | $14M | 0 |
| JEWISH COMMUNITY FOUNDATION OF GREATER PHOENIX | Scottsdale | T31 Philanthropy, Voluntarism & Grantmaking Foundations | $13.9M | 5 |
| LEGACY TRADITIONAL SCHOOL - CHANDLER | Chandler | B29 Education | $13.8M | 1 |
| PAN-AMERICAN ELEMENTARY CHARTER SCHOOL | Phoenix | B20 Education | $13.7M | 3 |
| GIRL SCOUTS - ARIZONA CACTUS-PINE COUNCIL INC | Phoenix | O42Z Youth Development | $13.7M | 6 |
| ACHIEVE HUMAN SERVICES INC | Yuma | F20Z Mental Health & Crisis Intervention | $13.5M | 4 |
| Arizona Coalition to End Sexual and Domestic Violence Inc | Phoenix | P010 Human Services | $13.5M | 2 |
| YOUTH DEVELOPMENT INSTITUTE | Phoenix | P300 Human Services | $13.4M | 4 |
| INTERNATIONAL DARK SKY DISCOVERY CENTER INC | Fountain Hills | T50 Philanthropy, Voluntarism & Grantmaking Foundations | $13.4M | 0 |
| Tylers Place AZ Inc | Chandler | B80 Education | $13.3M | 7 |
| PLANNED PARENTHOOD ARIZONA INC | Phoenix | E42 Health Care | $13.2M | 8 |
| LEGACY TRADITIONAL SCHOOL - WEST SURPRISE | Chandler | B20 Education | $13.2M | 1 |
| REID PARK ZOOLOGICAL SOCIETY | Tucson | D115 Animal-Related | $13.1M | 2 |
| VALLEY OF THE SUN JEWISH COMMUNITY CENTER INC | Scottsdale | — | $13.1M | 8 |
| INTENTIONAL LIFE MEDIA | Tucson | X840 Religion-Related | $13M | 6 |
| CHRISTIAN CARE MESA INC | Phoenix | P75Z Human Services | $13M | 4 |
| YUMA COUNTY WATER USERS' ASSOCIATION | Yuma | W80 Public & Societal Benefit | $13M | 4 |
| VALLEYWISE HEALTH FOUNDATION | Phoenix | E058 Health Care | $12.9M | 4 |
| SUCCESS SCHOOL | Surprise | B29 Education | $12.9M | 3 |
| LEGACY TRADITIONAL SCHOOL - EAST MESA | Chandler | B29 Education | $12.8M | 1 |
| BARRY GOLDWATER INSTITUTE FOR PUBLIC POLICY RESEARCH | Phoenix | W050 Public & Societal Benefit | $12.7M | 8 |
| ARCHWAY CLASSICAL ACADEMY TRIVIUM | Phoenix | B29 Education | $12.6M | 1 |
| PHOENIX ART MUSEUM | Phoenix | A510 Arts, Culture & Humanities | $12.5M | 7 |
| ARCHWAY CLASSICAL ACADEMY SCOTTSDALE | Phoenix | B29 Education | $12.5M | 3 |
